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Chemical - Azo Dye Test
 
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Azo Dye Test
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Azo dyes which can release forbidden amines by reductive cleavage, had not been allowed to be used in textiles and garments in Germany, Netherlands and Austria since nineteen nineties. This azo dyes restriction has been extended to the European Union by the EU directive 2002/61/EC. Such forbidden amines are classified as either carcinogenic or suspected to be carcinogenic.

According to the above 2002/61/EC, azodyes which, by reductive cleavage of one or more azo groups, may release one or more of the aromatic amines listed in Table (I), in detectable concentrations, i.e. above 30 ppm in the finished articles or in the dyed parts thereof, may not be used in textile and leather articles which may come into direct and prolonged contact with the human skin or oral cavity, such as:

  • clothing, bedding, towels, hairpieces, wigs, hats, nappies and other sanitary items, sleeping bags,
  • footwear, gloves, wristwatch straps, handbags, purses/wallets, briefcases, chair covers, purses worn round the neck,
  • textile or leather toys and toys which include textile or leather garments,
  • yarn and fabrics intended for use by the final consumer.
 
Table (I) List of Forbidden Amines
  Aromatic amine CAS-No.
  Biphenyl-4-ylamine
4-Aminobiphenyl
Xenylamine
92-67-1
  Benzidine 92-87-5
  4-Chloro-o-toluidine
95-69-2
  2-Naphthylamine
91-59-8
  o-Aminoazotoluene
4-Amino-2’, 3-dimethylazobenzene
4-o-Tolylazo-o-toluidine
97-56-3
  5-Nitro-o-toluidine
99-55-8
  4-Chloroaniline
106-47-8
  4-Methoxy-m-phenylendiamine
615-05-4
  4,4’-Methylenedianiline
4,4’-Diaminodiphenylmethane
101-77-9
  3,3’-Dichlorobenzidine
3,3’-Dichlorbiphenyl-4,4’-ylenediamine
91-94-1
  3,3’-Dimethoxybenzidine
o-Dianisidine
119-90-4
  3,3’-Dimethylbenzidine
4,4’-Bi-o-toluidine
119-93-7
  4,4’-Methylenedi-o-toluidine
838-88-0
  6-Methoxy-m-toluidine
p-Cresidine
120-71-8
  4,4’-Methylene-bis-(2-chloro-aniline)
2,2’-Dichloro-4,4’-methylen-dianiline
101-14-4
  4,4’-Oxydianiline
101-80-4
  4,4’-Thiodianiline
139-65-1
  o-Toluidine
2-Aminotoluene
95-53-4
  4-Methyl-m-phenylendiamine
95-80-7
  2,4,5-Trimethylaniline
137-17-7
  o-Anisidine
2-Methoxyaniline
90-04-0
  4-Aminoazobenzene 60-09-3
 
For the details of the test methods, please click here.
 
 
 
 
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