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Chemical
- Azo Dye Test |
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Azo dyes which can
release forbidden amines by reductive cleavage,
had not been allowed to be used in textiles and
garments in Germany, Netherlands and Austria since
nineteen nineties. This azo dyes restriction has
been extended to the European Union by the EU
directive 2002/61/EC. Such forbidden amines are
classified as either carcinogenic or suspected
to be carcinogenic.
According to the above 2002/61/EC, azodyes which,
by reductive cleavage of one or more azo groups,
may release one or more of the aromatic amines
listed in Table (I), in detectable concentrations,
i.e. above
30 ppm in the finished articles or in the dyed
parts thereof, may not
be used in textile and leather articles which
may come into direct and prolonged contact with
the human skin or oral cavity, such as: |
- clothing, bedding, towels, hairpieces, wigs,
hats, nappies and other sanitary items, sleeping
bags,
- footwear, gloves, wristwatch straps, handbags,
purses/wallets, briefcases, chair covers, purses
worn round the neck,
- textile or leather toys and toys which include
textile or leather garments,
- yarn and fabrics intended for use by the final
consumer.
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| Table (I) List
of Forbidden Amines |
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Aromatic
amine |
CAS-No. |
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Biphenyl-4-ylamine
4-Aminobiphenyl
Xenylamine
|
92-67-1 |
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Benzidine |
92-87-5 |
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4-Chloro-o-toluidine
|
95-69-2 |
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2-Naphthylamine
|
91-59-8 |
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o-Aminoazotoluene
4-Amino-2’, 3-dimethylazobenzene
4-o-Tolylazo-o-toluidine |
97-56-3 |
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5-Nitro-o-toluidine
|
99-55-8 |
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4-Chloroaniline
|
106-47-8 |
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4-Methoxy-m-phenylendiamine
|
615-05-4 |
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4,4’-Methylenedianiline
4,4’-Diaminodiphenylmethane |
101-77-9 |
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3,3’-Dichlorobenzidine
3,3’-Dichlorbiphenyl-4,4’-ylenediamine
|
91-94-1 |
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3,3’-Dimethoxybenzidine
o-Dianisidine |
119-90-4 |
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3,3’-Dimethylbenzidine
4,4’-Bi-o-toluidine |
119-93-7 |
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4,4’-Methylenedi-o-toluidine
|
838-88-0 |
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6-Methoxy-m-toluidine
p-Cresidine |
120-71-8 |
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4,4’-Methylene-bis-(2-chloro-aniline)
2,2’-Dichloro-4,4’-methylen-dianiline
|
101-14-4 |
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4,4’-Oxydianiline |
101-80-4 |
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4,4’-Thiodianiline
|
139-65-1 |
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o-Toluidine
2-Aminotoluene |
95-53-4 |
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4-Methyl-m-phenylendiamine
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95-80-7 |
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2,4,5-Trimethylaniline
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137-17-7 |
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o-Anisidine
2-Methoxyaniline |
90-04-0 |
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4-Aminoazobenzene |
60-09-3 |
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| For
the details of the test methods, please click here. |
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